(E)-1-(2-Phenyldiazen-2-ium-1-yl)naphthalen-2-olate

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1-[(E)-2-(2-Hy­droxy-5-methyl­phen­yl)diazen-2-ium-1-yl]naphthalen-2-olate

The title zwitterion, C17H14N2O2, crystallizes with two independent mol-ecules in the asymmetric unit, both of which are approximately planar, the dihedral angles between the benzene ring and the naphthalene ring system being 4.39 (12)° in one mol-ecule and 5.83 (12)° in the other, and show an E conformation with respect to the azo double bond. An intra-molecular N-H⋯O hydrogen bond in each mol...

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In the title zwitterionic compound, C16H12N2O, the dihedral angle between the phenyl ring and the naphthalene ring system is 17.85 (8)°; an intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, π-π stacking is observed between naphthalene ring systems of adjacent mol-ecules, the centroid-centroid distance being 3.6486 (11) Å.

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In the title compound, C7H9NO2, all non-H atoms are essentially coplanar [r.m.s. deviation = 0.032 Å]. The largest deviation from the plane of the pyridine ring is 0.105 (6) Å for the terminal C atom of the eth-oxy group. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds, forming inversion dimers. These dimers are further linked by C-H⋯π inter-actions and weak π-π inter-act...

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The title Schiff base compound, C(17)H(13)N(3)O(3), crystallizes in a zwitterionic form and exists in a trans configuration about the C=N bond. The mol-ecule is slightly twisted, the dihedral angle between the benzene ring and naphthalene ring system being 10.80 (9)°. The nitro group is twisted relative to the plane of the benzene ring [dihedral angle = 8.88 (12)°]. Bifurcated intra-molecular N...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s1600536813020102